Titan 2100

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Sorting the sea

The barge brings one liquid, and a short column splits it by boiling point, with Titan's air doing the cooling.

See it in the tour: chapter kraken shore, shot 4.2.

One liquid, three products

The sea barge loads 500 t of liquid at the jetty and runs it along the coast to the sea terminal design. What is in the tank is a mixture. Ligeia Mare, whose liquid Cassini's radar analysed, is 71% methane, 12% ethane and 17% nitrogen by volume physics. Kraken Mare is methane-dominated like it, but nobody has measured its own split physics. The plant is built to sort whatever arrives design.

The three products go three ways. Methane fuels the ascent vehicles and the shuttles. Ethane becomes plastic. Nitrogen goes to the ammonia plant design.

The tour does not frame the terminal, so the drawing below stands in for it.

Sea liquid71% CH₄12% C₂H₆ · 17% N₂Flash drumpressure dropsNitrogen gasboils at 77.3 KColumnMethaneboils at 111 KEthaneboils at 184.6 KCondenser: Titan air, 93.65 K17 K below methane's boiling point,so the overhead condenses for freeReboiler: reactor waste heatlifts the bottom to 184.6 Kwhere ethane boilsBoiling points at 1 atm. The mixture is Ligeia Mare's, the one measured sea; Kraken Mare's own split is not known.
Nitrogen boils at 77.3 K, far below the sea's 93.65 K, so it bubbles off as the pressure drops. Methane boils at 111 K and ethane at 184.6 K, a gap of 74 K that a short column spans. On Titan the cold air does the condenser's job. physics design

Three boiling points

Everything rests on how the three liquids differ. At one atmosphere nitrogen boils at 77.3 K, methane at 111 K and ethane at 184.6 K physics. The sea is at 93.65 K physics, between the first two.

Step one: let the nitrogen go

At 93.65 K nitrogen is above its own boiling point, so it stays in the liquid only because it is dissolved physics. A flash drum drops the pressure and the nitrogen leaves as a gas. The seas do the same on their own: nitrogen is expected to bubble out as conditions change physics. The gas goes to the ammonia plant.

Step two: the column

What is left is methane and ethane, 73.6 K apart in boiling point physics. The gap is wide, so a short column separates them. Liquid is heated at the bottom, vapour climbs through the trays, and each tray strips a little more ethane out of the rising vapour. Methane comes off the top. Ethane is left at the bottom design.

Titan does the cooling

The top of the column must be cold enough to turn methane vapour back into liquid. On Earth that takes a refrigerator. At Kraken Shore the outside air is 93.65 K, 17 K below methane's boiling point physics. A heat exchanger to the open air condenses the overhead for nothing design.

The heat for the bottom comes from the reactors. Waste heat is a product at 94 K, and the reboiler is one of its customers design. See Reactors and heat on Titan.

What nobody knows yet

Kraken Mare's methane, ethane and nitrogen fractions are an open item challenge. If it holds more ethane than Ligeia, more of the barge load goes to plastic. If it holds more nitrogen, the flash drum works harder. The column does not change. See Kraken Mare and Titan's seas.

Key numbers

QuantityValueBasis
Boiling point at 1 atm: nitrogen / methane / ethane77.3 K / 111 K / 184.6 Kphysics
Gap between methane and ethane73.6 Kphysics
Sea and air temperature93.65 Kphysics
Air below methane's boiling point17 Kphysics
Ligeia Mare, by volume71% methane, 12% ethane, 17% nitrogenphysics
Barge cargo500 tdesign
Condenseropen Titan airdesign

Sources